65, 2424–2429.
D. Mandelli, A. C. N. do Amaral, Y. N. Kozlov, L. S. Shul’pina, A. J. Bonon, W. A. Carvalho, G. B. Shul’pin, “Hydrogen Peroxide Oxygenation of Saturated and Unsaturated Hydrocarbons Catalyzed by Montmorillonite or Aluminum Oxide”, Catal. Lett., 2009, 132, 235–243.
A. J. Bonon, D. Mandelli, O. A. Kholdeeva, M. V. Barmatova, Y. N. Kozlov, G. B. Shul’pin, “Oxidation of alkanes and olefins with hydrogen peroxide in acetonitrile solution catalyzed by a mesoporous titanium-silicate Ti-MMM-2”, Appl. Catal. A: General, 2009, 365, 96–104.
M. V. Kirillova, M. L. Kuznetsov, V. B. Romakh, L. S. Shul’pina, J. J. R. Fraústo da Silva, A. J. L. Pombeiro, G. B. Shul’pin, “Mechanism of oxidations with H2O2 catalyzed by vanadate anion or oxovanadium(V) triethanolaminate (vanadatrane) in combination with pyrazine-2-carboxylic acid (PCA): Kinetic and DFT studies”, J. Catal., 2009, 267, 140–157.
M. V. Kirillova, Y. N. Kozlov, L. S. Shul’pina, O. Y. Lyakin, A. M. Kirillov, E. P. Talsi, A. J. L. Pombeiro, G. B. Shul’pin, “Remarkably fast oxidation of alkanes by hydrogen peroxide catalyzed by a tetracopper(II) triethanolaminate complex: Promoting effects of acid co-catalysts and water, kinetic and mechanistic features”, J. Catal., 2009, 268, 26–38.
G. B. Shul’pin, Y. N. Kozlov, L. S. Shul’pina, A. R. Kudinov, D. Mandelli, “Extremely Efficient Alkane Oxidation by a New Catalytic Reagent H2O2/Os3(CO)12/Pyridine”, Inorg. Chem., 2009, 48, No. 22, 10480–10482.
G. B. Shul’pin, Y. N. Kozlov, L. S. Shul’pina, P. V. Petrovskiy, “Oxidation of alkanes and alcohols with hydrogen peroxide catalyzed by complex Os3(CO)10(mu-H)2”, Appl. Organometal. Chem., 2010, 24, 464–472.
M. V. Kirillova, A. M. Kirillov, D. Mandelli, W. A. Carvalho, A. J. L. Pombeiro, G. B. Shul’pin, ”Mild homogeneous oxidation of alkanes and alcohols including glycerol with tert-butyl hydroperoxide catalyzed by a tetracopper(II) complex”, J. Catal., 2010, 272, 9–17.
G. B. Shul’pin, Y. N. Kozlov, L. S. Shul’pina, T. V. Strelkova, D. Mandelli, “Oxidation of Reactive Alcohols with Hydrogen Peroxide Catalyzed by Manganese Complexes” 2L2O3]2+ (L = 1,4,7-trimethyl-1,4,7-triazacyclononane)–carboxylic acid”>, Catal. Lett., 2010, 138, No. 3–4, 193–204.
Ю. Н. Козлов, Л. С. Шульпина, Т. В. Стрелкова, Г. Б. Шульпин, «Кинетика и механизм окисления 1-фенилэтанола системой “пероксид водорода-биядерный комплекс марганца(IV)-щавелевая кислота”», Ж. физ. хим., 2010, 84, No. 9, 1650–1653. English Version: Y. N. Kozlov, L. S. Shul’pina, T. V. Strelkova, G. B. Shul’pin, “Kinetics and Mechanism of 1-Phenylethanol Oxidation by the System Hydrogen Peroxide–Manganese(IV) Binuclear Complex–Oxalic Acid”, Russ. J. Phys. Chem. A, 2010, 84, No. 9, 1502–1505.
G. B. Shul’pin, M. V. Kirillova, Y. N. Kozlov, L. S. Shul’pina, A. R. Kudinov, A. J. L. Pombeiro, “Decamethylosmocene-catalyzed efficient oxidation of saturated and aromatic hydrocarbons and alcohols with hydrogen peroxide in the presence of pyridine” , J. Catal., 2011, 277, No. 2, 164–172. DOI: 10.1016/j.jcat.2010.11.002
M. L. Kuznetsov, Y. N. Kozlov, D. Mandelli, A. J. L. Pombeiro, G. B. Shul’pin, “Mechanism of Al3+-Catalyzed Oxidations of Hydrocarbons: Dramatic Activation of H2O2 toward O–O Homolysis in Complex [Al(H2O)4(OOH)(H2O2)]2+ Explains the Formation of HO• Radicals”, Inorg. Chem., 2011, 50, 3996–4005. DOI: dx.doi.org/10.1021/ic102476x
A. M. Kirillov, M. V. Kirillova, L. S. Shul’pina, P. J. Figiel, K. R. Gruenwald, M. F. C. G. da Silva, M. Haukka, A. J. L. Pombeiro, G. B. Shul’pin, “Mild oxidative functionalization of alkanes and alcohols catalyzed by new mono- and dicopper(II) aminopolyalcoholates”, J. Mol. Catal. A: Chem., 2011, 350, 26–34. doi:10.1016/j.molcata.2011.08.028
M. V. Kirillova, M. L. Kuznetsov, Y. N. Kozlov, L. S. Shul’pina, A. Kitaygorodskiy, A. J. L. Pombeiro, G. B. Shul’pin, “Participation of Oligovanadates in Alkane Oxidation with H2O2 Catalyzed by Vanadate Anion in Acidified Acetonitrile: Kinetic and DFT Studies”, ACS Catal. 2011, 1, No. 11, 1511–1520. DOI: 10.1021/cs200237m
D. S. Nesterov, E. N. Chygorin, V. N. Kokozay, V. V. Bon, R. Boča, Y. N. Kozlov, L. S. Shul’pina, J. Jezierska, A. Ozarowski, A. J. L. Pombeiro, G. B. Shul’pin, “Heterometallic CoIII4FeIII2 Schiff Base Complex: Structure, Electron Paramagnetic Resonance, and Alkane Oxidation Catalytic Activity”, Inorg. Chem., 2012, 51, No. 16, 9110–9122. DOI: dx.doi.org/10.1021/ic301460q
D. Mandelli, Y. N. Kozlov, W. A. Carvalho, G. B. Shul’pin, “Oxidations by the system ‘hydrogen peroxide–[Mn2L2O3]2+ (L=1,4,7-trimethyl-1,4,7-triazacyclononane)–carboxylic acid’. Part 13. Epoxidation of methyl oleate in acetonitrile solution”, Catal. Commun., 2012, 26, 93–97. doi:10.1016/j.catcom.2012.04.019
E. V. Gusevskaya, L. Menini, L. A. Parreira, R. A. Mesquita, Y. N. Kozlov, G. B. Shul’pin, “Oxidation of isoeugenol to vanillin by the “H2O2–vanadate–pyrazine-2-carboxylic acid” reagent”
2O2–vanadium derivative–pyrazine-2-carboxylic acid’”>, J. Mol. Catal. A: Chem., 2012, 363–364, 140–147. DOI: http://dx.doi.org/10.1016/j.molcata.2012.06.001
G. B. Shul’pin, Y. N. Kozlov, L. S. Shul’pina, A. J. L. Pombeiro, “Hydrocarbon oxygenation with Oxone catalyzed by complex [Mn2L2O3]2+ (L=1,4,7-trimethyl-1,4,7-triazacyclononane) and oxalic acid”, Tetrahedron, 2012, 68, 8589–8599. DOI: http://dx.doi.org/10.1016/j.tet.2012.07.098
G. B. Shul’pin, M. V. Kirillova, L. S. Shul’pina, A. J. L. Pombeiro, E. E. Karslyan, Y. N. Kozlov, “Mild oxidative alkane functionalization with peroxides in the presence of ferrocene”, Catal. Commun., 2013, 31, 32–36. DOI: http://dx.doi.org/10.1016/j.catcom.2012.11.003
Л. С. Шульпина, Ю. Н. Козлов, Т. В. Стрелкова, Г. Б. Шульпин, «Кинетика и механизм окисления бензола пероксимоносульфатом, катализируемого биядерным комплексом марганца(IV) в присутствии щавелевой кислоты», Журнал физической химии, 2013, 87, №3, 414–417. English Version: L. S. Shul’pina, Y. N. Kozlov, T. V. Strelkova, G. B. Shul’pin, “Kinetics and Mechanism of Benzene Oxidation by Peroxymonosulfate Catalyzed with a Binuclear Manganese(IV) Complex in the Presence of Oxalic Acid”, Russ. J. Phys. Chem. A, 2013, 87, No. 3, 393–396. DOI: 10.1134/S003602441303028X
M. Sutradhar, N. V. Shvydkiy, M. F. C. G. da Silva, M. V. Kirillova, Y. N. Kozlov, A. J. L. Pombeiro, G. B. Shul'pin, “New binuclear oxovanadium(V) complex as a catalyst in combination with pyrazinecarboxylic acid (PCA) for efficient alkane oxygenation by H2O2”, Dalton Trans., 2013, 42, 11791–11803. DOI: 10.1039/C3DT50584G
A. S. Novikov, M. L. Kuznetsov, A. J. L. Pombeiro, N. A. Bokach, G. B. Shul’pin, “Generation of HO Radical from Hydrogen Peroxide Catalyzed by Aqua Complexes of the Group III Metals [M(H2O)n]3+ (M = Ga, In, Sc, Y, or La): A theoretical Study”, ACS Catal. 2013, 3, 1195–1208. DOI: dx.doi.org/10.1021/cs400155q
G. B. Shul’pin, Y. N. Kozlov, L. S. Shul’pina, W. Carvalho, D. Mandelli, “Oxidation reactions catalyzed by osmium compounds. Part 4. Highly efficient oxidation of hydrocarbons and alcohols including glycerol by the H2O2/Os3(CO)12/pyridine reagent”, RSC Adv., 2013, 3, No. 35, 15065–15074. DOI: 10.1039/C3RA41997E
Л. С. Шульпина, Е. Л. Дурова, Ю. Н. Козлов, А. Р. Кудинов, Т. В. Стрелкова, Г. Б. Шульпин, «Окисление бензола пероксидом водорода, катализируемое ферроценом в присутствии пиразинкарбоновой кислоты», Журнал физической химии, 2013, 87, №12, . English Version: L. S. Shul’pina, E. L. Durova, Y. N. Kozlov, A. R. Kudinov, T. V. Strelkova, G. B. Shul’pin, Russ. J. Phys. Chem. A, 2013, 87, No. 12, .
E. E. Karslyan, L. S. Shul’pina, Y. N. Kozlov, A. J. L. Pombeiro, G. B. Shul’pin, “Oxygenation of saturated and aromatic hydrocarbons with H2O2 catalyzed by the carbonyl thiophenolate iron complex (OC)3Fe(PhS)2Fe(CO)3”, Catal. Today, 2013, in press. DOI: http://dx.doi.org/10.1016/j.cattod.2013.04.030
A. N. Bilyachenko, M. S. Dronova, A. I. Yalymov, A. A. Korlyukov, L. S. Shul’pina, D. E. Arkhipov, E. S. Shubina, M. M. Levitsky, A. D. Kirilin, G. B. Shul’pin, “New binuclear cage-like copper(II) silsesquioxane (“cooling tower”); its high catalytic activity in oxidation of benzene and alcohols”, Eur. J. Inorg. Chem., 2013, in press.
Некоторые патенты Selected Patents in English
A. N. Nesmeyanov, M. I. Rybinskaya, G. B. Shul’pin, “Method for isolating organometallic compounds and thiourea adducts with organometallic compounds”, Pat. USA 3,950,373, 1976.
A. N. Nesmeyanov, M. I. Rybinskaya, G. B. Shul’pin, “Adducts of organometallic compounds with thiourea”, Pat. UK 1457605, 1976.
A. Hoehn, G. Suess-Fink, G. B. Shulpin, G. V. Nizova, "Oxidation of methane and ethane to products containing carbon, hydrogen and oxygen in the presence of metal complexes", Ger. Offen. DE 19,720,344, 1997 (to BASF A.–G., Germany), 5 pp. Application: DE 97-19720344 19970515. (Chem. Abstr. 128:48802p, 1998).
G. Suess-Fink, G. B. Shul’pin, L. S. Shul’pina, "Process for the production of ketones", Pat. USA 7,015,358 (March 21, 2006; Filled 2002, to Lonza A.–G., Switzerland). Eur. Pat. EP 1 385 812 A0 (Application: WO 02/088063, art. 158 of the EPC).
Некоторые материалы международных конференций
Selected Abstracts and Proceedings of International Conferences
G. B. Shul’pin, G. V. Nizova, A. N. Druzhinina, M. M. Kats, “Photochemical catalytic and stoichiometric activation of C-H bonds in saturated and aromatic hydrocarbons by chloro- and oxometalates”, Abstracts of the 7th International Symposium on Homogeneous Catalysis, Lyon, France, 1990, P-30, pp. 181-182.
G. B. Shul’pin, Plenary lecture “Activation de la liaison C-H”, Materials of un colloque scientifique CONCOORD-GECOM, Paris, France, 2002.
G. B. Shul’pin, Plenary lecture “Activation of C–H Bonds by Metal Complexes”, Abstracts of DFG-Berichtskolloquium zum SPP 1118, Aachen, Germany, 2002.
C. B. Woitiski, Y. N. Kozlov, G. V. Nizova, U. Schuchardt, D. Mandelli, G. B. Shul’pin, “Epoxidation of olefins including natural terpenes by the system ‘hydrogen peroxide–manganese(IV) complex–carboxylic acid’ in acetonitrile. Kinetics and mechanism of the dec-1-ene epoxidation”, Proceedings of the 13th International Congress on Catalysis, Paris, France, 2004, oral presentation O2-009.
R. A. Steffen, G. B. Shul’pin, D. Mandelli, “A combinatorial approach to the optimization of carvone epoxidation by the ‘hydrogen peroxide–manganese(IV) complex–oxalic acid’ system”, Proceedings of the 13th International Congress on Catalysis, Paris, France, 2004, poster presentation P3-061.
G. B. Shul’pin, G. V. Nizova, Y. N. Kozlov, V. S. Arutyunov, A. C. M. dos Santos, A. C. da Silva, D. Mandelli, “Oxidation of Hydrocarbons Including Methane by the ‘Hydrogen Peroxide–Manganese(IV) Complex–Oxalic Acid’ System in Water: Unusual Regio-selectivity in the Reaction with n-Heptane”, Proceedings of the 14th International Symposium on Homogeneous Catalysis, Munich, Germany, 2004, page 230.
D. Mandelli, H. Stoeckli-Evans, Y. N. Kozlov, A. Tesouro Vallina, C. B. Woitiski, R. S. Jimenez, W. A. Carvalho, G. B. Shul’pin, “Oxidation of Alkanes with m-Chloroperbenzoic Acid Catalyzed by Iron(III) Chloride and a Polydentate N4-Amine”, Proceedings of the 14th International Symposium on Homogeneous Catalysis, Munich, Germany, 2004, page 227.
C. C. Golfeto, D. Mandelli, Y. N. Kozlov, G. B. Shul’pin, “Peroxyacetic Acid Oxidation of Hydrocarbons Catalyzed by a Manganese(IV) Complex with 1,4,7-Trimethyl-1,4,7-triazacyclononane”, Proceedings of the 14th International Symposium on Homogeneous Catalysis, Munich, Germany, 2004, page 226.
V. A. dos Santos, D. Mandelli, M. I. F. Barbosa, G. B. Shul’pin, “Highly Efficient Oxidation of Secondary Alcohols with H2O2 Catalyzed by a Dinuclear Manganese(IV) Complex and Oxalic Acid”, Proceedings of the 14th International Symposium on Homogeneous Catalysis, Munich, Germany, 2004, page 229.
D. Mandelli, M. I. F. Barbosa, M. G. Matthes, J. L. T. Aoyagi, B. L. Tacarambi, G. B. Shul’pin, “Oxidation of alkanes and alcohols by the system “hydrogen peroxide – [(TMTACN)2Mn2(O)3](PF6)2 (TMTACN = 1,4,7-trimethyl-1,4,7-triazacyclononane) – carboxylic acid”, Proceedings of XX Ibero-American Symposium on Catalysis, Gramado, Brazil, 2006, poster P-317, page 267.
D. Mandelli, C. C. Golfeto, L. S. Shul’pina, G. B. Shul’pin, “Alkane oxygenation with H2O2 catalysed by FeCl3 and 2,2'-bipyridine”, Proceedings of the XX Ibero-American Symposium on Catalysis, Gramado, Brazil, 2006, oral presentation B-01, page 90.
M. V. Kirillova, L. S. Shul’pina, T. Sooknoi, A. J. L. Pombeiro, G. B. Shul’pin, “Alkane oxygenation with H2O2 catalysed by Silicalite TS-1”, Abstracts of the 3rd International Conference on Green and Sustainable Chemistry, Delft, The Netherlands, 2007.
D. Mandelli, M. G. Matthes, J. L. T. Aoyagi, G. B. Shul’pin, “Hydrogen peroxide oxidation of organic compounds catalyzed by manganese complexes with 1,4,7-trimethyl-1,4,7-triazacyclononane in the presence of a carboxylic acid”, Abstracts of 3rd International Conference “Catalysis: fundamentals and application”, 2007, Novosibirsk, Russia., oral presentation OP-I-12, vol. 1, page 82.
D. Mandelli, L. S. Shul’pina, C. C. Golfeto, G. B. Shul’pin, “Hydrogen peroxide oxidation of saturated hydrocarbons catalyzed by iron(III) chloride and 2,2’-bipyridine”, Abstracts of 3rd International Conference “Catalysis: fundamentals and application”, 2007, Novosibirsk, Russia. PP-I-33, vol. 2, page 67.
G. B. Shul’pin, “Free-radical, crypto-radical and non-radical metal-catalyzed alkane oxygenations by peroxides”, Extended Abstracts of the 14th International Congress on Catalysis, Seoul, Korea, 2008, Abstract PIII-51-10, PICC08-0285.
G. B. Shul’pin, D. V. Muratov, L. S. Shul’pina, A. R. Kudinov, “Oxygenation of benzene with H2O2 in acetonitrile solution catalyzed by rhodium carbonyl complexes”, Extended Abstracts of the 14th International Congress on Catalysis, Seoul, Korea, 2008, Abstract PIII-53-12, PICC08-0288(1).
D. Mandelli, Y. N. Kozlov, A. C. N. do Amaral, R. Bogarin, A. J. Bonon, W. A. Carvalho, J. L. T. Aoyagi, G. B. Shul’pin, “ Hydrocarbon oxidation with H2O2 catalyzed by alumina or montmorillonite”, Extended Abstracts of the 14th International Congress on Catalysis, Seoul, Korea, 2008, Abstract PIII-53-14, PICC08-0306.
D. Mandelli, O. A. Kholdeeva, A. J. Bonon, M. V. Barmatova, G. B. Shul’pin, “Hydrogen peroxide oxygenation of saturated hydrocarbons in acetonitrile catalyzed by mesoporous titanium-silicate Ti-MMM-2”, Extended Abstracts of the 14th International Congress on Catalysis, Seoul, Korea, 2008, Abstract PIII-53-15, PICC08-0307.
V. B. Romakh, M. V. Kirillova, L. S. Shul’pina, J. J. R. Fraústo da Silva, A. J. L. Pombeiro, G. B. Shul’pin, “The mechanism of oxidation with hydrogen peroxide catalyzed by vanadate or vanadtrane and PCA”, Abstracts of the 16th International Symposium on Homogeneous Catalysis, Florence, Italy, 2008, P152.
L. S. Shul’pina, M. V. Kirillova, A. M. Kirillov, A. J. L. Pombeiro, Y. N. Kozlov, G. B. Shul’pin, “Hydrogen peroxide oxidation of alkanes to alkyl hydroperoxides catalyzed by copper complexes”, Abstracts of the 16th International Symposium on Homogeneous Catalysis, Florence, Italy, 2008, P154.
G. B. Shul’pin, A. R. Kudinov, L. S. Shul’pina, D. V. Muratov, “Hydrogen peroxide oxidation of benzene catalyzed by rhodium carbonyl cluster Rh6(CO)16”, Abstracts of the 16th International Symposium on Homogeneous Catalysis, Florence, Italy, 2008, P229.
G. B. Shul’pin, Y. N. Kozlov, L. S. Shul’pina, K. C. Chiacchio, D. Mandelli, “Oxidation of hydrocarbons with H2O2 catalyzed by solid and soluble aluminum-containing compounds”, Abstracts of the 16th International Symposium on Homogeneous Catalysis, Florence, Italy, 2008, P231.
L. S. Shul’pina, L. P. Gabriel, A. R. Kudinov, D. Mandelli, G. B. Shul’pin, “Osmium complexes as catalysts for oxygenation of hydrocarbons with peroxides”, Abstracts of the 21st Ibero-American Symposium of Catalysis, Málaga, Spain, 2008, poster LT5-P47, page 156.
D. Mandelli, W. A. Carvalho, Y. N. Kozlov, A. C. N. do Amaral, R. Bogarin, K. C. Chiacchio, G. B. Shul’pin, “Oxidation of alkanes and olefins with hydrogen peroxide catalyzed by aluminum derivatives”, Abstracts of the 21st Ibero-American Symposium of Catalysis, Málaga, Spain, 2008, oral presentation LT5-O35-S27, page 136.
D. Mandelli, K. C. Chiacchio, Y. N. Kozlov, G. B. Shul’pin, “Hydrogen peroxide oxidation of hydrocarbons catalyzed by Al-containing compounds: an accelerating effect of acids”, Abstracts of the 6th World Congress on Oxidation Catalysis, Lille, France, 2009, oral presentation O73-1B, vol. O, page 212.
A. J. Bonon, D. Mandelli, O. A. Kholdeeva, M. V. Barmatova, Y. N. Kozlov, G. B. Shul’pin, “Oxidation of alkanes and olefins with H2O2 in acetonitrile catalyzed by mesoporous titanium-silicate Ti-MMM-2”, Abstracts of the 6th World Congress on Oxidation Catalysis, Lille, France, 2009, poster 1B-P192, vol. A, page 112.
D. Mandelli, L. S. Shul’pina, M. K. G. Bizarra, G. B. Shul’pin, “Oxidation of alcohols with molecular oxygen or air catalyzed by FeCl3 and other iron compounds under visible light irradiation”, Abstracts of the 6th World Congress on Oxidation Catalysis, Lille, France, 2009, poster 2A-P666, vol. A, page 200.
W. A. Carvalho, A. C. N. do Amaral, K. C. Chiacchio, D. Mandelli, Y. N. Kozlov, G. B. Shul’pin, “Aluminum-catalyzed oxidation of alkanes with H2O2: remarkable accelerating effects of added acids or FeCl3”, Proceedings of the International Conference EuropaCat IX “Catalysis for a Sustainable World”, Salamanca, Spain, 2009, poster, page 279.
G. B. Shul’pin, “Organometallic complexes as catalysts in oxidations of C-H compounds”, A keynote lecture, Abstracts of 25 Intern. Conf. Organometal. Chem., Lisbon, Portugal, 2012, Abstract K1.
D. Mandelli, L. S. Shul’pina, M. V. Kirillova, A. M. Kirillov, W. A. Carvalho, A. J. L. Pombeiro, |
